Degrees:
B.S. - University of Vigo (Chemistry), 2001
M.S. – University of Vigo, 2003
Ph.D. - University of Zaragoza, 2008
Research Interests: Metal-mediated C-H Activation of Hydrocarbons, metal-mediated C-O bond formation
Research Description:
Publications:
Bolaño, T.; Collado, A.; Esteruelas, M. A.; Oñate, E. Selectivity of Allenylidene versus Butadienyl Protonation in an Osmium-Bisphosphine System,Organometallics 2009, 28, 2107-2111.
Bolaño, T.; Castarlenas, R.; Esteruelas, M. A.; Oñate, E. Nazarov Type Cyclization on an Osmium-Dienylcarbene Complex, J. Am. Chem. Soc. 2009, 131, 2064-2065.
Bolaño, T.; Castarlenas, R.; Esteruelas, M. A.; Oñate, E. Formation of an Asymmetric Acyclic Osmium-Dienylcarbene Complex. Organometallics 2008, 27, 6367-6370.
Bolaño, T.; Castarlenas, R.; Esteruelas, M. A.; Oñate, E. Sequential and Selective Hydrogenation of the Ca-Cb and M-CaDouble Bonds of and Allenylidene Ligand Coordinated to Osmium: New Reaction Patterns between an Allenylidene Complex and Alcohols, J. Am. Chem. Soc. 2007, 129, 8850-8859.
Bolaño, T.; Castarlenas, R.; Esteruelas, M. A.; Oñate, E. Hydride-Carbyne to Carbene Transformation in an Osmium-Acetate-Bis(triisopropylphosphine) System: Influence of the Coordination Mode of the Carboxylate and the Reaction Solvent,Organometallics 2007, 26, 2037-2041.
Bolaño, T.; Castarlenas, R.; Esteruelas, M. A.; Oñate, E. Assembly of an Allenylidene Ligand, a Terminal Alkyne, and an Acetonitrile Molecule: Formation of Osmacyclopentapyrrole Derivatives, J. Am. Chem. Soc. 2006, 128, 3965-3973.
Bolaño, T.; Castarlenas, R.; Esteruelas, M. A.; Modrego, F. J.; Oñate, E. Hydride-Alkenylcarbyne to Alkenylcarbene Transformation in Bisphosphine-Osmium Complexes, J. Am. Chem. Soc. 2005, 127, 11184-11195.
Fall, Y.; Diouf, O.; Gómez, G.; Bolaño, T. The thioacetate approach to the synthesis of the side chain of vitamin D metabolites and analogues, Tetrahedron Letters 2003, 44, 6069-6072.
